Questions & Answers about Al llegar a la cima, vimos un prado enorme y una charca al fondo.
Because al + infinitive is a very common Spanish structure meaning when, upon, or on doing something.
So:
Here, Al llegar a la cima means When we arrived at the summit or On reaching the summit.
It does not literally mean to the arriving in natural English, even though al comes from a + el in other contexts. In this structure, you should learn al + infinitive as a set pattern.