その 都市 の 人口 は 百万人 です。sono tosi no zinkou ha hyakumannin desu.
That city has a population of 1 million.

Breakdown of sono tosi no zinkou ha hyakumannin desu.
ですdesu
to be
はha
topic particle
のno
possessive case particle
そのsono
that ... adnominal
〜人〜nin
people counter
百万hyakuman
million
人口zinkou
population
都市tosi
city
都市 is more generic than 市 and refers to the concept of a city as a populated and developed area. It doesn't necessarily imply a political or administrative boundary like 市 does. The term 都市 is more comparable to the English use of urban area or metropolis.
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