Questions & Answers about Me molesta que el peaje de esa autopista sea tan caro en verano.
Because molestar here works like to bother / to annoy.
- Me molesta... = It bothers me...
- The thing that causes the annoyance is the subject of the verb.
- Me is an indirect object pronoun meaning to me.
So in this sentence, the thing that bothers you is:
Literally, the structure is closer to:
- It bothers me that the toll on that motorway is so expensive in summer.
By contrast, yo molesto means I bother / I annoy, which is a completely different idea.
Because after me molesta que..., Spanish normally uses the subjunctive.
The sentence expresses a reaction or feeling about a situation:
- Me molesta que... = It bothers me that...
When one clause expresses emotion, judgment, influence, doubt, etc., and the next clause is introduced by que, Spanish usually uses the subjunctive.
So:
not:
- Me molesta que el peaje... es tan caro ❌
Here, sea is the present subjunctive of ser.