Questions & Answers about Di chi è questo libro?
Why does the sentence start with Di instead of a word for 'whose'?
Italian does not have a single exact word for 'whose'. Instead, it uses the preposition di (of) combined with chi (who) to literally ask 'Of whom?'. This is the standard way to ask about possession in Italian.
Why is the word order so different from English?
If chi means 'who', can I just leave out di?
No, if you leave out di, you are asking Chi è questo libro? which literally translates to 'Who is this book?'. You need the preposition di to indicate possession and change 'who' into 'whose'.