Questions & Answers about Die Luft ist angenehm kühl.
Because Luft is a feminine noun in German, so its nominative singular article is die.
- die Luft = the air
This is something you usually just have to learn together with the noun:
- die Luft
- die Sonne
- die Zeit
In this sentence, die Luft is the subject, so die is the correct form.
German main clauses usually follow the verb-second rule. That means the finite verb comes in position 2.
In Die Luft ist angenehm kühl:
- Die Luft
- ist
- angenehm kühl
This is very normal German word order for a simple statement.